{"68418":{"#nid":"68418","#data":{"type":"news","title":"Self Cleaning Electrode Allows Fuel Cells to Operate on Coal Gas","body":[{"value":"\u003Cp\u003EUsing barium oxide nanoparticles, researchers have developed a self-cleaning technique that could allow solid oxide fuel cells to be powered directly by coal gas at operating temperatures as low as 750 degrees Celsius. The technique could provide a cleaner and more efficient alternative to conventional power plants for generating electricity from the nation\u0027s vast coal reserves.\u003C\/p\u003E\n\u003Cp\u003ESolid oxide fuel cells can operate on a wide variety of fuels, and use hydrocarbons gases directly -- without a separate reformer. The fuel cells rely on anodes made from nickel and a ceramic material known as yttria-stabilized zirconia. Until now, however, carbon-containing fuels such as coal gas or propane could quickly deactivate these Ni-YSZ anodes, clogging them with carbon deposits in a process known as \u0022coking\u0022 -- especially at lower operating temperatures.\n\u003C\/p\u003E\n\u003Cp\u003ETo counter this problem, researchers have developed a technique for growing barium oxide nanostructures on the anodes. The structures adsorb moisture to initiate a water-based chemical reaction that oxidizes the carbon as it forms, keeping the nickel electrode surfaces clean even when carbon-containing fuels are used at low temperatures.\n\u003C\/p\u003E\n\u003Cp\u003E\u0022This could ultimately be the cleanest, most efficient and cost-effective way of converting coal into electricity,\u0022 said Meilin Liu, a Regents professor in the School of Materials Science and Engineering at the Georgia Institute of Technology. \u0022And by providing an exhaust stream of pure carbon dioxide, this technique could also facilitate carbon sequestration without the separation and purification steps now required for conventional coal-burning power plants.\u0022\n\u003C\/p\u003E\n\u003Cp\u003EThe water-mediated carbon removal technique was reported June 21 in the journal \u003Cem\u003ENature Communications\u003C\/em\u003E. The research was supported by the U.S. Department of Energy\u0027s Office of Basic Energy Sciences, through the HeteroFoaM Center, an Energy Frontier Research Center. The work also involved researchers from Brookhaven National Laboratory, the New Jersey Institute of Technology and Oak Ridge National Laboratory.\n\u003C\/p\u003E\n\u003Cp\u003EConventional coal-fired electric generating facilities capture just a third of the energy available in the fuel they burn. Fuel cells can convert significantly more of the energy, approximately 50 percent. If gas turbines and fuel cells could be combined into hybrid systems, researchers believe they could capture as much as 80 percent of the energy, reducing the amount of coal needed to produce a given amount of energy, potentially cutting carbon emissions.\n\u003C\/p\u003E\n\u003Cp\u003EBut that would only be possible if the fuel cells could run for long periods of time on coal gas, which now deactivates the anodes after as little as 30 minutes of operation.\n\u003C\/p\u003E\n\u003Cp\u003EThe carbon removal system developed by the Georgia Tech-led team uses a vapor deposition process to apply barium oxide nanoparticles to the nickel-YSZ electrode. The particles, which range in size from 10 to 100 nanometers, form \u0022islands\u0022 on the nickel that do not block the flow of electrons across the electrode surface.\n\u003C\/p\u003E\n\u003Cp\u003EWhen water vapor introduced into the coal gas stream contacts the barium oxide, it is adsorbed and dissociates into protons and hydroxide (OH) ions. The hydroxide ions move to the nickel surface, where they combine with the carbon atoms being deposited there, forming the intermediate COH. The COH then dissociates into carbon monoxide and hydrogen, which are oxidized to power the fuel cell, ultimately producing carbon dioxide and water. About half of the carbon dioxide is then recirculated back to gasify the coal to coal gas to continue the process.\n\u003C\/p\u003E\n\u003Cp\u003E\u0022We can continuously operate the fuel cell without the problem of carbon deposition,\u0022 said Liu, who is also co-director of Georgia Tech\u0027s Center for Innovative Fuel Cell and Battery Technologies.\n\u003C\/p\u003E\n\u003Cp\u003EThe researchers also evaluated the use of propane to power solid oxide fuel cells using the new anode system. Because oxidation of the hydrogen in the propane produces water, no additional water vapor had to be added, and the system operated successfully for a period of time similar to the coal gas system.\n\u003C\/p\u003E\n\u003Cp\u003ESolid oxide fuel cells operate most efficiently at temperatures above 850 degrees Celsius, and much less carbon is deposited at higher temperatures. However, those operating temperatures require fabrication from special materials that are expensive -- and prevent solid oxide fuel cells from being cost-effective for many applications.\n\u003C\/p\u003E\n\u003Cp\u003EReducing the operating temperatures is a research goal, because dropping temperatures to 700 or 750 degrees Celsius would allow the use of much less expensive components for interconnects and other important components. However, until development of the self-cleaning process, reducing the operating temperature meant worsening the coking problem.\n\u003C\/p\u003E\n\u003Cp\u003E\u0022Reducing the operating temperature significantly by eliminating the problem of carbon deposition could make these solid oxide fuel cells economically competitive,\u0022 Liu said.\n\u003C\/p\u003E\n\u003Cp\u003EFuel cells powered by coal gas still produce carbon dioxide, but in a much purer form than the stack gases leaving traditional coal-fired power plants. That would make capturing the carbon dioxide for sequestration less expensive by eliminating large-scale separation and purification steps, Liu noted.\n\u003C\/p\u003E\n\u003Cp\u003EThe researchers have so far tested their process for a hundred hours, and saw no evidence of carbon build-up. A major challenge ahead is to test the long-term durability of the system for fuel cells that are designed to operate for as long as five years. Researchers must also study the potential impact of possible fuel contaminants on the new electrode.\n\u003C\/p\u003E\n\u003Cp\u003EForming the barium oxide structures can be done as part of conventional anode fabrication processes, and would not require additional steps. The anodes produced in the technique are compatible with standard solid oxide fuel cell systems that are already being developed for commercial electricity generation, home power generation and automotive applications.\n\u003C\/p\u003E\n\u003Cp\u003E\u0022We have started with state-of-the-art technology, and simply modified the surface of the electrode,\u0022 said Mingfei Liu, a postdoctoral researcher in the Center. \u0022Because our electrode would be built on existing technology, there is a lower barrier for implementing it in conventional fuel cell systems.\u0022\n\u003C\/p\u003E\n\u003Cp\u003EIn addition to those already mentioned, the research team included Lei Yang, Wentao Qin and Kevin Blinn from Georgia Tech; YongMan Choi and Ping Liu from Brookhaven National Laboratory; Haiyan Chen and Trevor Tyson from the New Jersey Institute of Technology, and Jianming Bai from Oak Ridge National Laboratory.\n\u003C\/p\u003E\n\u003Cp\u003E\u003Cstrong\u003EResearch News \u0026amp; Publications Office\u003Cbr \/\u003E\nGeorgia Institute of Technology\u003Cbr \/\u003E\n75 Fifth Street, N.W., Suite 314\u003Cbr \/\u003E\nAtlanta, Gerogia 30308 USA\n\u003C\/strong\u003E\u003C\/p\u003E\u003Cp\u003E\u003Cstrong\u003E\n\u003C\/strong\u003E\u003C\/p\u003E\u003Cp\u003E\u003Cstrong\u003EMedia Relations Contacts\u003C\/strong\u003E: John Toon (404-894-6986)(\u003Ca href=\u0022mailto:jtoon@gatech.edu\u0022\u003Ejtoon@gatech.edu\u003C\/a\u003E) or Abby Robinson (404-385-3364)(\u003Ca href=\u0022mailto:abby@innovate.gatech.edu\u0022\u003Eabby@innovate.gatech.edu\u003C\/a\u003E).\n\u003C\/p\u003E\n\u003Cp\u003E\u003Cstrong\u003ETechnical Contact\u003C\/strong\u003E: Meilin Liu (\u003Ca href=\u0022mailto:meilin.liu@mse.gatech.edu\u0022\u003Emeilin.liu@mse.gatech.edu\u003C\/a\u003E).\n\u003C\/p\u003E\n\u003Cp\u003E\u003Cstrong\u003EWriter\u003C\/strong\u003E: John Toon\n\u003C\/p\u003E","summary":null,"format":"limited_html"}],"field_subtitle":"","field_summary":[{"value":"\u003Cp\u003EUsing barium oxide nanoparticles, researchers have developed a self-cleaning technique that could allow solid oxide fuel cells to be powered directly by coal gas at operating temperatures as low as 750 degrees Celsius.\u003C\/p\u003E","format":"limited_html"}],"field_summary_sentence":[{"value":"A new cleaning technique allows fuel cells to be powered by coal."}],"uid":"27303","created_gmt":"2011-06-21 00:00:00","changed_gmt":"2016-10-08 03:09:37","author":"John Toon","boilerplate_text":"","field_publication":"","field_article_url":"","dateline":{"date":"2011-06-21T00:00:00-04:00","iso_date":"2011-06-21T00:00:00-04:00","tz":"America\/New_York"},"extras":[],"hg_media":{"68421":{"id":"68421","type":"image","title":"Meilin Liu with fuel cell","body":null,"created":"1449177176","gmt_created":"2015-12-03 21:12:56","changed":"1475894594","gmt_changed":"2016-10-08 02:43:14"},"68420":{"id":"68420","type":"image","title":"Meilin Liu with fuel cell","body":null,"created":"1449177176","gmt_created":"2015-12-03 21:12:56","changed":"1475894594","gmt_changed":"2016-10-08 02:43:14"},"68419":{"id":"68419","type":"image","title":"Researchers with fuel cell","body":null,"created":"1449177176","gmt_created":"2015-12-03 21:12:56","changed":"1475894594","gmt_changed":"2016-10-08 02:43:14"}},"media_ids":["68421","68420","68419"],"related_links":[{"url":"http:\/\/www.mse.gatech.edu\/","title":"Georgia Tech School of Materials Science and Engineering"},{"url":"http:\/\/www.mse.gatech.edu\/faculty-staff\/faculty\/meilin-liu","title":"Meilin Liu"}],"groups":[{"id":"1188","name":"Research Horizons"}],"categories":[{"id":"144","name":"Energy"},{"id":"145","name":"Engineering"},{"id":"149","name":"Nanotechnology and Nanoscience"},{"id":"135","name":"Research"}],"keywords":[{"id":"7070","name":"anode"},{"id":"4198","name":"coal"},{"id":"436","name":"electricity"},{"id":"213","name":"energy"},{"id":"2044","name":"Fuel Cell"},{"id":"13460","name":"Meilin Liu"},{"id":"2054","name":"nanoparticle"},{"id":"171091","name":"solid oxide fuel cell"}],"core_research_areas":[],"news_room_topics":[],"event_categories":[],"invited_audience":[],"affiliations":[],"classification":[],"areas_of_expertise":[],"news_and_recent_appearances":[],"phone":[],"contact":[{"value":"\u003Cp\u003E\u003Cstrong\u003EJohn Toon\u003C\/strong\u003E\u003Cbr \/\u003EResearch News \u0026amp; Publications Office\u003Cbr \/\u003E\u003Ca href=\u0022http:\/\/www.gatech.edu\/contact\/index.html?id=jt7\u0022\u003EContact John Toon\u003C\/a\u003E\u003Cbr \/\u003E\u003Cstrong\u003E404-894-6986\u003C\/strong\u003E\u003C\/p\u003E","format":"limited_html"}],"email":["jtoon@gatech.edu"],"slides":[],"orientation":[],"userdata":""}}}