{"648051":{"#nid":"648051","#data":{"type":"event","title":"PhD Defense by Shi Shi","body":[{"value":"\u003Cp\u003E\u003Cstrong\u003ETHE SCHOOL OF MATERIALS SCIENCE AND ENGINEERING\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EGEORGIA INSTITUTE OF TECHNOLOGY\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EUnder the provisions of the regulations for the degree\u003C\/strong\u003E\u003Cbr \/\u003E\r\n\u003Cbr \/\u003E\r\n\u003Cstrong\u003EDOCTOR OF PHILOSOPHY\u003C\/strong\u003E\u003Cbr \/\u003E\r\n\u003Cbr \/\u003E\r\n\u003Cstrong\u003Eon Monday, June 28, 2021\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003E2:00 PM\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cbr \/\u003E\r\n\u003Cstrong\u003Evia\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EBlue Jeans Video Conferencing\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Ca href=\u0022https:\/\/bluejeans.com\/382698441\/8178\u0022\u003Ehttps:\/\/bluejeans.com\/382698441\/8178\u003C\/a\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003Ewill be held the\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EDISSERTATION\u0026nbsp;DEFENSE\u003C\/strong\u003E\u003Cbr \/\u003E\r\n\u003Cbr \/\u003E\r\n\u003Cstrong\u003Efor\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EShi Shi\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003E\u0026quot;Bifunctional Metal Nanocrystals for Catalyzing and Reporting on Chemical Reactions by Surface-Enhanced Raman Scattering\u0026quot;\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003ECommittee Members:\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EProf. Dong Qin, Advisor, MSE\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EProf. Zhiqun Lin, MSE\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EProf. Meilin Liu, MSE\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EProf. Preet Singh, MSE\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EProf. Angus Wilkinson, CHEM\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u003Cstrong\u003EAbstract:\u003C\/strong\u003E\u003C\/p\u003E\r\n\r\n\u003Cp\u003E\u0026nbsp;\u003C\/p\u003E\r\n\r\n\u003Cp\u003ENoble-metal nanocrystals are of critical importance to an array of fundamental studies and a broad spectrum of applications in photonics, sensing, imaging, and catalysis. Thanks to the significant progress in controlling their colloidal synthesis, recent years have witnessed the successful development of bifunctional nanocrystals with integrated plasmonic and catalytic activities. Silver nanocrystals, in particular, could directly serve as bifunctional probes to catalyze reactions while reporting on the molecular species involved by \u003Cem\u003Ein situ\u003C\/em\u003E surface-enhanced Raman scattering (SERS). Although silver is an excellent catalyst for some oxidation reactions, it shows limited activities toward reduction reactions. This dissertation documents the discovery of Ag nanocrystals as a redox catalyst for the production of an aromatic azo compound. I unraveled the mechanistic insights by tracking and analyzing the vibrational bands of all chemical species involved in the reaction by \u003Cem\u003Ein situ\u003C\/em\u003E SERS. I established that surface functionalization with isocyanide allowed Ag nanocrystals to extract the oxygen atom from the nitro-group of a nitroaromatic compound for the oxidation of isocyanide to isocyanate. Concomitantly, the coupling between two adjacent deoxygenated nitroaromatic molecules produced an aromatic azo compound. In addition to demonstrating the feasibility of \u003Cem\u003Ein situ\u003C\/em\u003E SERS for monitoring chemical reactions, I further investigated the role of laser excitation wavelength in affecting SERS detection using Ag-Pd nanorods and Ag nanocubes with distinctive localized surface plasmon resonance (LSPR) properties as two bifunctional probes. I validated that Ag-Pd nanorods embraced stronger SERS activity when their longitudinal LSPR mode was at resonance with 785-nm laser excitation. In comparison, Ag nanocubes exhibited stronger SERS activity when their LSPR major peak of Ag nanocubes is closer to 532-nm laser excitation.\u003C\/p\u003E\r\n","summary":null,"format":"limited_html"}],"field_subtitle":"","field_summary":"","field_summary_sentence":[{"value":"Bifunctional Metal Nanocrystals for Catalyzing and Reporting on Chemical Reactions by Surface-Enhanced Raman Scattering"}],"uid":"27707","created_gmt":"2021-06-10 17:09:46","changed_gmt":"2021-06-10 17:09:46","author":"Tatianna Richardson","boilerplate_text":"","field_publication":"","field_article_url":"","field_event_time":{"event_time_start":"2021-06-28T15:00:00-04:00","event_time_end":"2021-06-28T17:00:00-04:00","event_time_end_last":"2021-06-28T17:00:00-04:00","gmt_time_start":"2021-06-28 19:00:00","gmt_time_end":"2021-06-28 21:00:00","gmt_time_end_last":"2021-06-28 21:00:00","rrule":null,"timezone":"America\/New_York"},"extras":[],"groups":[{"id":"221981","name":"Graduate Studies"}],"categories":[],"keywords":[{"id":"100811","name":"Phd Defense"}],"core_research_areas":[],"news_room_topics":[],"event_categories":[{"id":"1788","name":"Other\/Miscellaneous"}],"invited_audience":[{"id":"78761","name":"Faculty\/Staff"},{"id":"78771","name":"Public"},{"id":"78751","name":"Undergraduate students"}],"affiliations":[],"classification":[],"areas_of_expertise":[],"news_and_recent_appearances":[],"phone":[],"contact":[],"email":[],"slides":[],"orientation":[],"userdata":""}}}